UTILIZATION OF CHROMIUM WASTE FROM TANNING INDUSTRY AS CERAMIC GLAZE

LUSIA PERMATA SARI HARTANTI, Ir. Agus Prasetya, M.Eng.Sc., Ph.D.

2011 | Tesis | S2 Mag.Sistem Teknik

Limbah dari industri penyamakan kulit mengandung kromium. Penanganan limbah yang tidak sesuai dapat menyebabkan pencemaran lingkungan karena limbah tersebut tergolong dalam bahan berbahaya dan beracun, dimana konsentrasi kromium didalam limbah adalah 56314.026 ppm. Limbah kromium mempunyai potensi sebagai pewarna di industri keramik dan telah dikenal sebagai chrome green. Tujuan dari penelitian adalah meneliti kemampuan pelepasan dari immobilisasi kromium dan meneliti kualitas glasir dan karakteristiknya. Penelitian dilakukan berdasarkan pada variasi jumlah limbah kromium didalam campuran glasir. Komposisi glasir dasar adalah 35% feldspar, 35% borax, 15% kaolin dan 15% quartz sand. Limbah kromium sebanyak 0%, 15%, 30% dan 45% ditambahkan ke glasir dasar. Glasir diaplikasikan menggunakan kuas di permukaan badan keramik dan dibakar pada suhu 1100 °C selama 8 jam. Berdasarkan TCLP tes, konsentrasi kromium antara 0 ppm – 2.960 ppm. Semakin banyak limbah kromium ditambahkan maka konsentrasi kromium akan meningkat. Berdasarkan tank leaching test, konsentrasi kromium pada contoh D didalam lindi sangat rendah, antara 0.08 ppm – 0.13 ppm. Konsentrasi kromium dari TCLP dan tank leaching test masih dibawah dari baku mutu yang ditentukan (5 ppm) berdasarkan Peraturan Pemerintah No 85/1999. Ini berarti immobilisasi kromium berhasil dilakukan. Hasil penelitian menunjukkan bahwa kekerasan glasir adalah 8 skala Mohs, 6 skala Mohs, 5 skala Mohs dan 4 skala Mohs. Semakin banyak jumlah limbah kromium ditambahkan, maka nilai kekerasannya akan semakin rendah. Namun, nilai kekerasan dari setiap contoh masih memenuhi standar kualitas dari SNI 15-4249-1996, yaitu minimum 4 skala Mohs. Penambahan limbah kromium sebanyak 0%, 15%, 30% dan 45% menghasilkan variasi warna hijau. Seakin banyak jumlah limbah kromium ditambahkan, maka warna hijau akan semakin gelap.

Waste from tanning industry contains chromium. Inappropriate waste handling can cause environmental pollution because the waste is hazardous and toxic materials, where the concentration of chromium in waste was 56314.026 ppm. Chromium waste has potential as stain on ceramic industry and been known as chrome green. The objectives of research are to investigate leach ability of immobilized chromium and to investigate the glaze quality and its characteristic. The research was conducted according to the variation of the chromium waste amount in the glaze mixture. The basic glaze composition was 35% of feldspar, 35% of borax, 15% of kaolin and 15% of quartz sand. Chromium waste as much as 0%, 15%, 30% and 45% was added to the basic glaze mixture. Glaze was applied by brush on the surface of ceramic body and fired at 1100 °C for 8 hours. Based on TCLP test, the concentration of chromium was ranging from 0 ppm - 2.960 ppm. The more chromium waste was added, the chromium concentration increased. Based on tank leaching test, chromium concentration of D sample in the leachate was very low, ranging from 0.08 ppm – 0.13 ppm. The chromium concentration of TCLP and tank leaching test was lower than allowable limit (5 ppm) according to Peraturan Pemerintah No 85/1999. It means the immobilization of chromium was successful. The result of research showed that the hardness of glaze was 8 of Mohs scale, 6 of Mohs scale, 5 of Mohs scale, and 4 of Mohs scale. The more percentage of chromium waste was added, the lower hardness of glaze would be obtained. However, the hardness of each sample still meet the quality standard of SNI 15-4249-1996, that is minimum 4 of Mohs scale. The addition of chromium waste as much as 0%, 15%, 30% and 45% resulted variations of green colour. The more chromium waste was added, the green colour of glaze was darker.

Kata Kunci : limbah kromium, kekerasan, pelepasan, warna